'Tuning' Graphene Drums Might Turn Conductors to Semiconductors
From NIST Tech Beat: June 27, 2012
Tightening or relaxing the tension on a drumhead will change the way the drum sounds. The same goes for drumheads made from graphene, only instead of changing the sound, stretching graphene dramatically alters the material's electrical properties. Researchers working at the National Institute of Standards and Technology (NIST) and the University of Maryland have shown* that subjecting graphene to mechanical strain can mimic the effects of magnetic fields and create a quantum dot, an exotic type of semiconductor with a wide range of potential uses in electronic devices.
Graphene is a single layer of carbon atoms arranged in a honeycomb lattice. Pure graphene is a phenomenal conductor, transmitting electricity with little resistance at room temperature. But microelectronic devices depend on semiconductors that can be turned "on" and "off" because they have an energetic threshold beneath which they won't conduct electricity. This new work demonstrates that mechanical strain can be used to make tiny regions of graphite act like a classic semiconductor.
The research team suspended a sheet of graphene over shallow holes in a substrate of silicon dioxide—essentially making a set of graphene drumheads. In probing the drumheads with a scanning probe microscope, they found that the graphene rose up to meet the tip of the microscope— a result of the van der Waals force, a weak electrical force that creates attraction between objects that are very close to each other. Calculations by the University of Maryland group showed that the graphene should stretch into a peak, like the top of a circus tent.
The researchers discovered that they could tune the strain in the drumhead using the conducting plate upon which the graphene and substrate were mounted to create a countervailing attraction and pull the drumhead down. In this way, they could pull the graphene into or out of the hole below it.
Their measurements showed that changing the degree of strain changed the material's electrical properties. When they pulled the graphene membrane into the tent-like shape, the region at the apex acted just like a quantum dot, a type of semiconductor in which electrons are confined to a small region of space.
"Normally, to make a graphene quantum dot, you would have to cut out a nanosize piece of graphene," says NIST fellow Joseph Stroscio. "Our work shows that you can achieve the same thing with strain-induced pseudomagnetic fields. It's a great result, and a significant step toward developing future graphene-based devices."
The work was a collaborative effort with the University of Maryland, College Park, and the Korea Research Institute of Standards and Science.
* N. Klimov, S. Jung, S. Zhu, T. Li, C. Wright, S. Solares, D. Newell, N. Zhitenev and J. Stroscio. Electromechanical properties of graphene drumheads. Science. Vol. 336 no. 6088 pp. 1557-1561 DOI: 10.1126/science.1220335. Published online before print June 21, 2012.