Development of Reference Material 8103: Adamantane for Subambient DSC Temperature and Enthalpy Calibration

Published

September 13, 2024

Author(s)

Tara Fortin, Amanda Koepke, Jolene Splett

Abstract

A new Reference Material (RM), designated RM 8013, has been developed for the temperature and enthalpy calibration of differential scanning calorimeters (DSCs). The addition of this new RM expands the applicable range of NIST's DSC-related calibration standards to include sub-ambient temperatures and represents an attractive alternative to the previous option, Standard Reference Material® (SRM®) 2225, which was discontinued in 2017. RM 8103 was sourced from a single lot of high-purity ( 99%) adamantane. The transition temperature of RM 8103 has been determined to be equal to (-64.58 ± 0.20) °C, while the enthalpy of transition has been determined to be equal to (21.64 ± 0.34) J·g-1. Both values were determined via DSC measurements using an instrument calibrated with certified reference materials obtained from two different national metrology institutes. This document provides all relevant measurement and analysis details for the development of RM 8103.

Citation

Special Publication (NIST SP) - 260-241

Report Number

260-241

NIST Pub Series

Special Publication (NIST SP)

Pub Type

NIST Pubs

Download Paper

https://doi.org/10.6028/NIST.SP.260-241

Local Download

Keywords

Adamantane, Calibration, Differential scanning calorimetry, Differential thermal analyzers, Enthalpy of transition, Transition temperature

Citation

Fortin, T. , Koepke, A. and Splett, J. (2024), Development of Reference Material 8103: Adamantane for Subambient DSC Temperature and Enthalpy Calibration, Special Publication (NIST SP), National Institute of Standards and Technology, Gaithersburg, MD, [online], https://doi.org/10.6028/NIST.SP.260-241, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=956616 (Accessed December 14, 2024)