Thermodynamic and Thermophysical Properties ( Including Mixtures) of the Reference Ionic Liquid: 1-Hexyl-3-Methylimidazolium Bis[(Trifluoromethyl) Sulfonyl]amide. Part 2. Critical Evaluation and Recommended Property Values

Published

March 20, 2009

Author(s)

Robert D. Chirico, Vladimir Diky, Joe W. Magee, Michael D. Frenkel, Kenneth N. Marsh

Abstract

This article is a product of IUPAC Project 2002-005-1-100 (Thermodynamics of ionic liquids, ionic liquid mixtures, and the development of standardiized systems). Experimental results of thermodynamic, transport, and phase equilibrium studies made on a reference sample of the ionic liquid 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide are summarized, compared, and critically evaluated to provide recommended values with uncertainties for the properties measured. Properties measured included thermal properties (triple-point temperature, glass-transition temperature, enthalpy of fusion, heat capacities of cocndensed states), volumetric properties, speeds of sound, viscosities, electrolytic conductivities, relative permittivities, as well as properties for mixtures, such as gas solubilities (solubility pressures), solute activity coefficients at infinite dilutioin, and liquid-liquid equilibrium temperatures. Recommended values with uncertainties are provided for the properties studied experimentally. The effect of the presence of water on the property values is discussed.

Citation

Pure and Applied Chemistry

Volume

81

Issue

5

Pub Type

Journals

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Keywords

thermodynamic properties, transport properties, recommended values, critical evaluation, ionic liquids

Citation

Chirico, R. , Diky, V. , Magee, J. , Frenkel, M. and Marsh, K. (2009), Thermodynamic and Thermophysical Properties ( Including Mixtures) of the Reference Ionic Liquid: 1-Hexyl-3-Methylimidazolium Bis[(Trifluoromethyl) Sulfonyl]amide. Part 2. Critical Evaluation and Recommended Property Values, Pure and Applied Chemistry, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=832304 (Accessed January 15, 2025)