Kumar, S.
and Douglas, J.
(2001),
Gelation in Physically Associating Polymer Solutions, Physical Review Letters, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=851813
(Accessed December 22, 2024)
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Gelation in Physically Associating Polymer Solutions
Published
Author(s)
S K. Kumar,
Abstract
The thermally reversible gelation of a polymer solution is investigated. The dynamics slows down upon cooling in these systems much like glass-firming liquids. We show that no significant changes in the dynamics occurs near the geometrical percolation threshold and a separate transition is found where the solution viscosity diverges.Citation
Physical Review Letters
Volume
87
Issue
No. 18
Pub Type
Journals
Download Paper
Keywords
glass transition, non-ergodicity transition, percolation, phase separation, stickers, thermally reversible gelation, vogel temperature
Citation
Issues
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Created September 30, 2001, Updated October 12, 2021