Radiationless Resonant Raman Scattering at the Ar K Edge

Published

January 1, 1999

Author(s)

Thomas W. LeBrun, S H. Southworth, G B. Armen, M A. MacDonald, Y Azuma

Abstract

Partial cross sections for Ar K-LZL3(1 D2)np, n=4 and 5 spectator Auger states excited by x-ray absorption across the K-edge were measured and compared with calculations based on the theory or radiationless resonant Raman scattering. Core relaxation and coherence among bound and continuum intermediate states produce shake-up, shake-down, and photoelectron-recapture effects in the cross sections. The width and position of the 4p spectator Auger peak are shown to be sensitive to resonance structure in the partial cross section via averaging over the x-ray bandwidth.

Citation

Physical Review A (Atomic, Molecular and Optical Physics)

Volume

60

Issue

No. 6

Pub Type

Journals

Keywords

argon K edge, argon KKL Auger, Auger resonant Raman, Auger spectroscopy, radiationless resonant Raman

Citation

LeBrun, T. , Southworth, S. , Armen, G. , Macdonald, M. and Azuma, Y. (1999), Radiationless Resonant Raman Scattering at the Ar K Edge, Physical Review A (Atomic, Molecular and Optical Physics) (Accessed October 13, 2025)