A Fluorinated Metal-Organic Framework for High Methane Storage at Room Temperature

Published

April 14, 2016

Author(s)

Ganggang Chang, Huimin Wen, Bin Li, Wei Zhou, Hailong Wang, Khalid Alfooty, Zongbi Bao, Banglin Chen

Abstract

A fluorinated metal-organic framework NOTT-108 with single pure-phase has been synthesized for the first time, which has enabled us to examine the effect of the substituted fluorine atoms on the methane storage. The activated NOTT-108a shows a permanent porosity comparable to its iso-reticular NOTT-101a: but exhibits a higher volumetric methane storage capacity of 247 Cm³ (STP) cm^-3 and a working capacity of 186 cm³ (STP) cm^-3 (at 298 K and 65 bar) than 237 cm³ (STP) cm^{-3 and 181 cm}u3^ (STP) cm^-3 of NOTT-101a, attributed to the higher polarity/dipole moment of C-F bonds compared to that of C-H bonds for enhanced electrostatic interaction with methane molecules.

Citation

Crystal Growth & Design

Volume

16

Issue

6

Pub Type

Journals

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Keywords

porous materials, methane storage

Citation

Chang, G. , Wen, H. , Li, B. , Zhou, W. , Wang, H. , Alfooty, K. , Bao, Z. and Chen, B. (2016), A Fluorinated Metal-Organic Framework for High Methane Storage at Room Temperature, Crystal Growth & Design, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=920793 (Accessed December 26, 2024)