Wu, H.
, Zhou, W.
and Yildirim, T.
(2011),
Metal Amidoboranes, NOVA Science Publishers, Inc., Hauppauge, New York, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=905295
(Accessed October 31, 2024)
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Metal Amidoboranes
Published
Author(s)
, ,
Abstract
Metal amidoboranes, consisting of [NH2BH3]- anion and various metal cations, are a new class of compounds that have recently attracted great attentions due to their intriguing crystal structures and novel chemical and physical properties. Similar to ammonia borane (AB), metal amidoboranes have great potential to meet the stringent gravimetric and volumetric hydrogen storage capacity targets needed for transportation applications. Moreover, compared to AB, metal amidoboranes have been shown to release hydrogen at lower temperatures, and at higher rates and with the release of fewer volatile contaminants. Particularly, several metal amidoboarnes also appear to release hydrogen less exothermically than AB. In this chapter, we review recent research progress on metal amidoborane compounds, including their syntheses, structures, crystal chemistry, and hydrogen storage properties.Citation
Boron Hydrides, High Potential Hydrogen Storage Materials
Publisher Info
NOVA Science Publishers, Inc., Hauppauge, New York
Pub Type
Books
Download Paper
Keywords
alkaline amidoboranes, alkaline earth amidoboranes, hydrogen storage, dehydrogenation, crystal structure
Citation
Issues
If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.
Created September 1, 2011, Updated February 19, 2017