Skip to main content
U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Microencapsulated POSS in Cellulose Using 1-Ethyl-3-Methylimidazolium Acetate

Published

Author(s)

Douglas M. Fox, Mauro Zammarano, Jeffrey W. Gilman

Abstract

Polyhedral oligomeric silsesquioxane (POSS) and cellulose were reacted in the ionic liquid, 1-ethyl-3-methylimidazolium acetate (EmiAc). Side reactions between the EmiAc and each reactant were prevalent, but use of water as the coagulating solvent produced microencapsulated POSS in cellulose. The effects of cellulose sources, POSS reactive groups, NaOH pretreatment of cellulose, and regenerating solvent were examined using elemental analysis, infrared spectroscopy, nuclear magnetic resonance, and thermogravimetric analysis. The POSS – cellulose products were found to have good thermal stability and a high char yield.
Proceedings Title
Molten Salts & Ionic Liquids 17
Conference Dates
October 10-15, 2010
Conference Location
Las Vegas, NV
Conference Title
214th Meeting of the Electrochemical Society

Keywords

Cellulose, POSS, ionic liquids, TGA

Citation

Fox, D. , Zammarano, M. and Gilman, J. (2010), Microencapsulated POSS in Cellulose Using 1-Ethyl-3-Methylimidazolium Acetate, Molten Salts & Ionic Liquids 17, Las Vegas, NV (Accessed December 30, 2024)

Issues

If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.

Created October 10, 2010, Updated February 19, 2017