Norrgard, E.
, Cooksey, C.
, Eckel, S.
, Pilgram, N.
, Rodriguez, K.
, Yoon, H.
, Chamorro Mena, Y.
, Pasteka, L.
and Borschevsky, A.
(2023),
Radiative Decay Rate and Branching Fractions of MgF, Physical Review A, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=936468
(Accessed February 2, 2025)
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Radiative Decay Rate and Branching Fractions of MgF
Published
Author(s)
, , , , Kayla Rodriguez, , Yuly Andrea Chamorro Mena, Lukáš Pašteka, Anastasia Borschevsky
Abstract
Here we report measured and calculated values of radiative decay rates and vibrational branching fractions for the A$^2\Pi$ state of MgF. The decay rate measurements use time-correlated single photon counting with roughly 1\,\% total uncertainty. Branching-fraction measurements are performed using two calibrated imaging systems to achieve few percent total uncertainty. We use the highly accurate multireference relativistic Fock-space coupled cluster method to calculate the Franck-Condon factors and the spin-orbit multireference configuration interaction method to calculate the transition dipole moments required to determine the decay rates and the branching fractions. The measurements provide a precision benchmark for testing the accuracy of the molecular structure calculations. The determination of the decay rate and vibrational branching fractions can be used to inform future optical cycling and laser cooling schemes for the MgF molecule.Citation
Physical Review A
Pub Type
Journals
Download Paper
Citation
Issues
If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.
Created September 8, 2023, Updated September 18, 2023