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Displaying 201 - 225 of 3711

Solvent-cast 3D Printing of Biodegradable Polymer Scaffolds

October 22, 2021
Author(s)
John Tolbert, Diana Hammerstone, Nathaniel Yuchimiuk, Jonathan Seppala, Lesley Chow
Three-dimensional (3D) printing is a popular technique to fabricate scaffolds for tissue engineering because of its ability to produce complex tissue-like architectures. Scaffolds are often 3D printed using biodegradable polymers like poly(caprolactone)

Imperfect Surface Order and Functionalization in Vertical Carbon Nanotube Arrays Probed by Near Edge X-ray Absorption Fine Structure Spectroscoy (NEXAFS)

October 12, 2021
Author(s)
T Hemraj-Benny, S Banerjee, S Sambasivan, Daniel A. Fischer, G Eres, Alexander Puretzky, David B. Geohegan, D H. Lowndes, J A. Misewich, S S. Wong
Probing surface order in nanotube systems is of fundamental importance for incorporation of these materials into practical electronic devices. The current study pertains to analysis of the surface orientation of vertically aligned single-walled and multi

Measuring Tie Chains and Trapped Entanglements in Semicrystalline Polymers

September 21, 2021
Author(s)
Amanda G. McDermott, Paul DesLauriers, Jeff Fodor, Ronald L. Jones, Chad R. Snyder
A label-free method for quantifying stress-transmitter (or elastically effective molecule) content (p) in semicrystalline polymers, including both tie molecules and bridging entanglements, is developed and demonstrated based on swelling with deuterated

Side Chain Engineering Control of Mixed Conduction in Oligoethylene Glycol-Substituted Polythiophenes

August 31, 2021
Author(s)
Jonathan Onorato, Zhongyang Wang, Yangyang Sun, Christian Nowak, Ban Dong, Lucas Flagg, Ruipeng Li, Lee J. Richter, Fernando Escobedo, Paul Nealey, Shrayesh Patel, Christine Luscombe
A major limitation for polymeric mixed ionic/electronic conductors (MIECs) is the trade-off between ionic and electronic conductivity; changes made that improve one typically hinder the other. In order to address this fundamental problem, this work

Polarized X-ray scattering measures molecular orientation in polymer-grafted nanoparticles

August 12, 2021
Author(s)
Subhrangsu Mukherjee, Dean DeLongchamp, Eliot Gann, Daniel Sunday, Lee J. Richter, Jason Streit, Richard A. Vaia, Baskar Ganapathysubramanian, Kumar Saurabh, Adarsh Krishnamurthy
Polymer chains are attached to nanoparticle surfaces for many purposes, including altering solubility, influencing aggregation, dispersion, and even tailoring immune responses in drug delivery. The most unique structural motif of polymer-grafted

Temperature-insensitive silicone composites as ballistic witness materials: the impact of water content on the thermophysical properties

July 28, 2021
Author(s)
Ran Tao, Fan Zhang, Huong Giang Nguyen, Philip Bernstein, Amanda L. Forster, Randy Mrozek, Aaron M. Forster
In this work, different formulations of a room-temperature silicone composite backing material (SCBM) composed of polydimethylsiloxane (PDMS), fumed silica and corn starch were investigated using different characterization techniques, i.e., differential

Simulated filament shapes in embedded 3D printing

July 22, 2021
Author(s)
Leanne Friedrich, Jonathan Seppala
Embedded 3D printing, wherein fluid inks are extruded into a bath, has enabled the manufacture of complex, custom structures ranging from cell-laden tissue analogues to soft robotics. This method encompasses two techniques: embedded ink writing (EIW)

Fluorescence Microscopy Reveals Structure-Property Relationships and Polymer Dynamics in Biocomposites

July 21, 2021
Author(s)
Quinn Easter, Shawn Chen, Jeremiah Woodcock, Amanda Souna, Sindhu Seethamraju, Jan Obrzut, Douglas M. Fox, Stephan J. Stranick, Jeffrey Gilman
OBJECTIVES: Developing the next generation of materials for use in restorative work requires a multifaceted approach. While mimicking the properties of the tooth, currently available dental composites and porcelains eventually fail and require replacement

Supersonic Impact Response of Polymer Thin Films via Large-Scale Atomistic Simulations

July 15, 2021
Author(s)
Andrew L. Bowman, Edwin P. Chan, William B. Lawrimore, John K. Newman
Recent nanoscale ballistic testing studies have shown the applicability of nanomaterials for ballistic protection but have raised new questions regarding the nanoscale structure-property relationships that contribute to the enhanced ballistic response of
Displaying 201 - 225 of 3711