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Search Publications by: Paul E. Stutzman (Fed)

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Displaying 51 - 75 of 106

Fate of nanoparticles during life cycle of polymer nanocomposites

July 6, 2011
Author(s)
Tinh Nguyen, Bastien T. Pellegrin, Coralie Bernard, Xiaohong Gu, Justin M. Gorham, Paul E. Stutzman, Deborah S. Jacobs, Walter E. Byrd, John W. Hettenhouser, Joannie W. Chin
Nanoparticles are increasingly used in consumer and structural polymeric products to enhance a variety of properties. Under the influences of environmental factors (e.g., ultraviolet, moisture, temperature) and mechanical actions (e.g., scratching

Statistical Modeling Cement Heat of Hydration

September 15, 2010
Author(s)
Paul E. Stutzman
The heat of hydration of hydraulic cements results from the complex sets of phase dissolution and precipitation activity accompanying the addition of water to a cement. Heat of hydration is currently measured in one of two ways: 1) through an acid

Using Thermodynamics to Simulate Cement Paste Microstructure Development

July 22, 2010
Author(s)
Jeffrey W. Bullard, Barbara Lothenbach, Paul E. Stutzman, Kenneth A. Snyder
We couple equilibrium thermodynamic calculations to a 3D microstructure model to simulate microstructure development during hydration of portland cement paste. The model uses a collection of growth/dissolution rules to approximate a range of growth modes

Role of Nanoparticles in Life Cycle of Nanocomposites

June 15, 2010
Author(s)
Xiaohong Gu, Guodong Chen, Minhua Zhao, Stephanie S. Watson, Paul E. Stutzman, Tinh Nguyen, Joannie W. Chin, Jonathan W. Martin
The objective of this study is to investigate the role of ZnO nanoparticles in the life cycle of a waterborne polyurethane (PU) nanocomposite during UV exposure. The effects of loadings and sizes of ZnO nanoparticles on photodegradation of ZnO/PU films

Degradation and Nanoparticle Release of Nanocomposite Coatings Exposed to UV Radiation

June 2, 2010
Author(s)
Tinh Nguyen, Bastien T. Pellegrin, Coralie Bernard, Xiaohong Gu, Justin M. Gorham, Paul E. Stutzman, Alexander J. Shapiro, Walter E. Byrd, Joannie W. Chin
The release of nanoparticles from nanocomposite coatings during their life cycle potentially has negative effects to the environments and presents a roadblock to their uses. The degradation and nanoparticle release of amine-cured epoxy coatings containing

Direct Evidence of Nanoparticle Release from Epoxy Nanocomposites Exposed to UV Radiation

April 14, 2010
Author(s)
Tinh Nguyen, Bastien T. Pellegrin, Coralie Bernard, Xiaohong Gu, Justin M. Gorham, Paul E. Stutzman, Alexander J. Shapiro, Walter E. Byrd, Joannie W. Chin
This study assessed the fate of SiO2 nanoparticles (nanoSiO2) in epoxy/nanoSiO2 composites exposed to ultraviolet (UV) radiation. The matrix was a stoichiometric mixture of adiglycidyl ether of bisphenol A epoxy and an aliphatic tri-amine. Films of

Measurement of yield stress for concentrated suspensions using a plate device

January 1, 2010
Author(s)
Min-Hong Zhang, Chiara C. Ferraris, Huaning Zhu, Vincent Picandet, Max A. Peltz, Paul E. Stutzman, Daniel De Kee
Slump has often been correlated with the yield stress of concrete as defined by the Bingham model. The discussion is still open as to what the yield stress value actually is and how to measure the yield stress of a suspension in general and for a

HYDRATED PHASES IN BLENDED CEMENTITIOUS SYSTEMS FOR NUCLEAR INFRASTRUCTURE

October 15, 2009
Author(s)
Kenneth A. Snyder, Paul E. Stutzman, Jacob Philip, David W. Esh
The hydration products of varying proportions of portland cement, fly ash, ground granulated blast furnace slag, and silica fume in blended systems were identified and quantified. The proportion of portland cement varied from 100 % down to 10 %. The

Studying Long-term Performance of a Nano-ZnO filled Waterborne Polyurethane Coating using Spectroscopies and Microscopies

September 9, 2009
Author(s)
Xiaohong Gu, Dongmei Zhe, Stephanie S. Watson, Guodong Chen, Minhua Zhao, Paul E. Stutzman, Deborah S. Jacobs, Tinh Nguyen, Joannie W. Chin, Jonathan W. Martin
Although inorganic UV absorbers such as zinc oxide (ZnO) and cerium oxide (CeO2) exhibit numerous advantages compared to organic UV absorbers, the mechanisms of how these nanoparticles affect the long-term performance of polymeric coatings are less than

Virtual Cement and Concrete

September 1, 2009
Author(s)
Jeffrey W. Bullard, Chiara C. Ferraris, Edward Garboczi, Nicos Martys, Paul E. Stutzman, Judith E. Terrill
Design and optimization of cement or concrete mixes typically is accomplished by intensive trial-and-error experimentation, primarily because the design space has many parameters and because interactions between these parameters are incompletely understood

Long-Term Performance of Nano-Filled Polymeric Materials: Effect of ZnO Nanoparticles on Photodegradation of a Waterborne Polyurethane Coating

July 8, 2009
Author(s)
Xiaohong Gu, Dongmei Zhe, Minhua Zhao, Guodong Chen, Nhieu Ly, Paul E. Stutzman, Li Piin Sung, Tinh Nguyen, Joannie W. Chin
Polymers are widely used as exterior coatings in buildings, bridges, aircrafts and automobiles for both protection and aesthetic purposes. However, the service life of the applied coatings is limited due to the photodegradation of polymers induced by

Cement and Concrete Materials Research at the National Institute of Standards and Technology (NIST)

September 5, 2007
Author(s)
Edward J. Garboczi, Dale P. Bentz, Jeffrey W. Bullard, Chiara F. Ferraris, Nicos Martys, Max A. Peltz, Sudalin Rodrigues, Paul E. Stutzman, Kenneth A. Snyder, John A. Winpigler
The materials science of cement and concrete is the focus of the Inorganic Materials Group at the National Institute of Standards and Technology (NIST). These experimental and computational research efforts include component and finished materials

Curing, Hydration, and Microstructure of Cement Paste

September 13, 2006
Author(s)
Dale P. Bentz, Paul E. Stutzman
This paper compares the hydration characteristics and microstructures of cement pastes with water-to-cement ratios (w/c) of 0.35 and 0.435, cured under saturated and sealed conditions. Degree of hydration is quantified by loss on ignition measurements. The

Virtual Testing of Cement and Concrete

May 10, 2006
Author(s)
Dale P. Bentz, Edward J. Garboczi, Jeffrey W. Bullard, Chiara F. Ferraris, Nicos Martys, Paul E. Stutzman
Concrete is a unique multi-phase, random, complex, and composite material that provides both strength and impermeability to engineered structures. Unlike most construction materials, the properties of concrete continue to develop over time and in place an