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Search Publications by: Mauro Zammarano (Fed)

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Displaying 1 - 25 of 52

Effects of Weathering and Formulation on the Properties of Vinyl Siding

September 23, 2024
Author(s)
Ronald Lankone, Mauro Zammarano, Song Jhang, Ickchan Kim, David Goodwin, Gianluca Sarti, Stefano Gardi, Camillo Cardelli, Lipiin Sung
Vinyl siding has become a popular choice for residential exteriors across the United States. In its insulated form, this siding includes a shell, capstock, and substrate, that encase a foamed material, serving as an efficient insulating material. While it

Imidazolium Modified Clay Based ABS Nanocomposites: A Comparison Between Melt-Blending and Solution Sonication Processes

October 12, 2021
Author(s)
M Modesti, S Besco, A Lorenzetti, Mauro Zammarano, V Causin, C Marega, Jeffrey W. Gilman, D M. Fox, Paul C. Trulove, Hugh C. De Long, P H. Maupin
Acrylonitrile-butadiene-styrene (ABS) nanocomposites containing imidazolium-modified montmorillonite have been prepared by melt-blending and solution-sonication in order to study the effects of processing on the morphology and properties of the polymer

Layered Double Hydroxides as Cation Exchange Materials

October 12, 2021
Author(s)
Paul Braterman, Nandika A. D'Souza, Jeffrey W. Gilman, Mickey C. Richardson, Laxmi K. Sahu, Mauro Zammarano
Layered double hydroxides (LDH) are a class of materials formally related to brucite-like hydroxides by the incorporation of higher valent cations, such as Al(III). The layer charge is neutralized by the insertion of any of a large range of exchangeable

Demonstration of an all-in-one solution for fire safe upholstery furniture: A benign backcoating for smoldering and flame-resistant cover fabrics

August 15, 2021
Author(s)
Ickchan Kim, Andre Thompson, Sung Chan Kim, Anthony Hamins, Matthew Bundy, Shonali Nazare, Rick D. Davis, Mauro Zammarano
The development of fire prevention and mitigation technologies with a benign toxicological and environmental profile has become of particular interest in the USA due to the recent adoption of state regulations that severely restrict the use of flame

Performance and Failure Mechanism of Fire Barriers in Full-Scale Chair Mock-ups

July 13, 2021
Author(s)
Andre Thompson, Ickchan Kim, Anthony Hamins, Matthew Bundy, Mauro Zammarano
The effectiveness and the failure mechanism of fire barriers in residential upholstered furniture were investigated by full-scale flaming tests on upholstered chair mock-ups. Six commercial fire barriers were tested in this study. Fire barriers were

Optimizing Flame Retardancy and Durability of Melamine-Formaldehyde/Solid-Urban-Waste Composite Panels

February 26, 2021
Author(s)
Mauro Zammarano, Carola Esposito Corcione, Francesca Ferrari, Raffaella Striani, Laura J. Dubrulle, Paolo Visconti, Antonio Greco
In our previous study, an innovative method for sterilization, inertization, and valorization of organic fraction of the municipal solid waste (OFMSW), to be recycled in the production of composite panels, had been developed. In this follow-up work, the

Full-Scale Experiments to Demonstrate Flammability Risk of Residential Upholstered Furniture and Mitigation Using Barrier Fabric

December 11, 2020
Author(s)
Mauro Zammarano, Matthew S. Hoehler, John R. Shields, Andre L. Thompson, Ickchan Kim, Isaac T. Leventon, Matthew F. Bundy
In this work, we investigated fire growth in a furnished compartment intended to mimic a living room where a couch was the main fuel load. Three TB-117-2013 compliant and commercially available couches were procured. The couches were identical except for

Reduced-Scale Test to Assess the Effect of Fire Barriers on the Flaming Combustion of Cored Composites: an Upholstery-Material Case Study

September 4, 2020
Author(s)
Mauro Zammarano, John R. Shields, Isaac T. Leventon, Ickchan Kim, Shonali Nazare, Andre L. Thompson, Rick D. Davis, Artur A. Chernovsky, Matthew F. Bundy
In this work, we describe a reduced-scale test (“Cube” test), based on cone calorimetry, measuring the fire performance (heat release rate, propensity to pool-fire formation, etc.) of composite specimens including a fire barrier (FB) and a flammable core

Intumescent Polydopamine Coatings for Fire Protection

March 9, 2020
Author(s)
Douglas M. Fox, Whirang Cho, Laura J. Dubrulle, Phillip Grutzmacher, Mauro Zammarano, Douglas M. Fox
Polydopamine coatings containing additional bioderived flame retardants were used as coatings for polyurethane foam and cardboard. The ability to form intumescing coatings was crucial for achieving good flame protection. Dopamine can effectively

Assessing Fire-blocking Effectiveness of Barrier Fabrics in the Cone Calorimeter

April 29, 2019
Author(s)
Shonali Nazare, William M. Pitts, Mauro Zammarano, John R. Shields, Elizabeth Knowlton, Benito De Leon
Cone calorimetric experiments have been conducted on bare flexible polyurethane foam (FPUF) samples as well as FPUF covered with a variety of fire-blocking barrier fabrics (BFs) in order to characterize and rank BF effectiveness for improving the

A Novel Application of Silicone-Based Flame-Retardant Adhesive in Plywood

September 11, 2018
Author(s)
Mauro Zammarano, John R. Shields, Elizabeth D. Knowlton, Ickchan Kim, Matthew S. Hoehler
A silicone-based elastomer filled with vinyl-silane treated aluminum hydroxide was used as a flame- retardant adhesive for plywood, as a replacement for a conventional polyurethane-based adhesive. The shear strength and fire performance of such a silicone

Nanocomposite Electrolytes for Lithium Batteries with Reduced Flammability

March 21, 2018
Author(s)
Mauro Zammarano, Apostolos Enotiadis, Nikhil Fernandes, Natalie A. A. Becerra, Emmanuel P. Giannelis
We report a family of flame-retardant electrolytes for lithium batteries based on ionic nanocomposites. The nanocomposites are synthesized in one pot by dispersing SiO2 nanoparticles charge-balanced by both Li ions and mono-amino-terminated polyether (PEO

Delamination of Organo-Modified Layered Double Hydroxides in Polyamide 6 by Melt Processing

February 19, 2017
Author(s)
Mauro Zammarano, S Bellayer, Jeffrey W. Gilman, Massimiliano Franceschi, Frederick Beyer, Richard H. Harris Jr., Meriani Sergio
Layered double hydroxide/polyamide 6 nanocomposites (LDH/PA6) were prepared from organo-modified LDH by melt processing. The anionic exchange capacity of LDH was varied in order to investigate its influence on the degree of exfoliation. LDH were dispersed

Effect of Carbon Nanofiber Network Formation on Flammability of Flexible Polyurethane Foams

February 19, 2017
Author(s)
Mauro Zammarano, Roland H. Kraemer, Richard H. Harris Jr., Thomas J. Ohlemiller, John R. Shields, Sameer Rahatekar, Jeffrey W. Gilman
Polyurethane flexible foams (PUFs) are used extensively as upholstery and bedding materials. Untreated PUFs are prone to rapid fire growth due to their low density and thermal conductivity. Furthermore, the low viscosity of the decomposition products

Flexible Polyurethane Foams Nanocomposites

February 19, 2017
Author(s)
Mauro Zammarano, Roland H. Kraemer, Richard H. Harris Jr., Thomas J. Ohlemiller, Sameer Rahatekar, Jeffrey W. Gilman
Polyurethane flexible foams (PUFs) have a large market as upholstery and bedding cushioning material. There is an increasing demand for flame retarded grades in rail, plane and automotive transportation. Untreated PUFs are prone to rapid fire growth due to

Ionic Liquids as Compatibilizers for the Preparation of Biopolymer Nanocomposites: Characterization Using Laser Scanning Confocal Microscopy

February 19, 2017
Author(s)
Jeffrey W. Gilman, P H. Maupin, Mauro Zammarano, Paul C. Trulove, D M. Fox, H DeLong, Ph Dubois, M Murariu
The process of dispersing ionic liquid modified montmorillonite in polylactide (PLA) using a twin-screw micro-compounder under different melt-compounding parameters was monitored using laser scanning confocal microscopy (LSCM). In addition the PLA-MMT