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Search Publications by: Dean DeLongchamp ()

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Displaying 101 - 119 of 119

Thickness Dependence of Microstructure in Semiconducting Films of an Oligofluorene Derivative

December 7, 2006
Author(s)
Dean M. DeLongchamp, Mang-Mang Ling, Youngsuk Jung, Daniel A. Fischer, Mark Roberts, Eric K. Lin, Zhenan Bao
The measurement and optimization of microstructure development in organic semiconductor films is valuable because microstructure in many cases critically impacts electronic performance. We demonstrate a general method to measure microstructure thickness

Correlating Molecular Design to Microstructure in Thermally Convertible Oligothiophenes: The Effect of Branched versus Linear End Groups

June 8, 2006
Author(s)
Dean M. DeLongchamp, Youngsuk Jung, Daniel A. Fischer, Eric K. Lin, P C. Chang, V Subramanian, A R. Murphy, J M. Frechet
The thin film microstructure development of functionalized oligothiophenes with branched, thermally removable groups at each end of conjugated cores with five, six, and seven thiophene rings was monitored during their thermal conversion from solution

Solution and Surface Composition Gradients via Microfluidic Confinement: Fabrication of a Statistical-Copolymer-Brush Composition Gradient

June 6, 2006
Author(s)
Chang Xu, Susan E. Barnes, Tao Wu, Daniel A. Fischer, Dean M. DeLongchamp, J Batteas, Kathryn L. Beers
A simple method to generate solution gradients through microfluidic confinement is described. The solution gradient inside a microchannel was formed by varying the relative infusion rates of two solutions that differed in compositions. The establishment

Effects of Humidity on Unencapsulated Poly(thiophene) Thin Film Transistors

March 13, 2006
Author(s)
Michael L. Chabinyc, Fred Endicott, B D. Vogt, Dean DeLongchamp, Eric K. Lin, Yiliang Wu, Ping Liu, Beng S. Ong
The effects of humidity on unencapsulated polymeric thin-film transistors (TFTs) were investigated. TFTs were fabricated on glass substrates with inorganic gate dielectric and a semiconducting layer of poly[5,5 -bis(3-dodecyl-2-thienyl)-2,2 -bithiophene]

The influence of molecular weight on the microstructure and thin film transistor characteristics of pBTTT polymers

January 1, 2006
Author(s)
Rick Hamilton, Clare Bailey, Warren Duffy, Martin Heeney, Martin Shkunov, David Sparrowe, Steve Tierney, Iain McCulloch, Regis J. Kline, Dean DeLongchamp, Michael L. Chabinyc
A common strategy to improve the electrical performance of organic field effect transistors is to optimize the charge carrier mobility of the semiconducting thin film. Polymer semiconductor transport properties have shown a dependence on the chain length

Self-Assembly, Molecular Ordering, and Charge Mobility in Solution-Processed Ultrathin Oligothiophene Films

November 29, 2005
Author(s)
A R. Murphy, Paul C. Chang, Priscilla VanDyke, J Liu, J M. Frechet, V Subramanian, Dean DeLongchamp, S Sambasivan, Daniel A. Fischer, Eric K. Lin
Symmetrical quarter-(T4), penta-(T5), sexi-(T6), and heptathiophene (T7) oligomers containing thermally removable aliphatic ester solubilizing groups were synthesized, and their UV-vis and thermal characteristics were compared. Spun-cast thin films of each

Variations in Semiconducting Polymer Microstructure and Hole Mobility With Spin-Coating Speed

November 15, 2005
Author(s)
Dean M. DeLongchamp, Brandon M. Vogel, Youngsuk Jung, Curt A. Richter, Oleg A. Kirillov, Jan Obrzut, Daniel A. Fischer, S Sambasivan, Marc Gurau, Lee J. Richter, Eric K. Lin
Organic semiconductors permit low-cost processing methods such as spin-coating, dip coating, or ink-jet printing onto flexible substrates. However, the performance of these materials in devices is difficult to control and new processing methods can deliver

Direct Correlation of Organic Semiconductor Film Structure to Field-Effect Mobility

August 1, 2005
Author(s)
Dean M. DeLongchamp, S Sambasivan, Daniel A. Fischer, Eric K. Lin, Paul C. Chang, A R. Murphy, J M. Frechet, V Subramanian
Recent efforts towards the large-scale adoption of organic electronics have focused on maximizing device performance using new molecular designs and processing strategies. However, rational design and systematic progress are hindered by insufficient

Non-Linear Charge Transport in Polythiophene Under High AC Field

January 1, 2005
Author(s)
Jan Obrzut, Tatiana Psurek, C. K. Chiang, Dean DeLongchamp
Complex impedance and conductivity were measured for regioregular poly(3-hexylthiophene) (P3HT) at alternating current (AC) voltages using a waveform technique. The waveforms were Fourier transformed from time domain to frequency domain and analyzed at

Engineering the Electrochromism of Layer-by-Layer Assembled Films

February 1, 2004
Author(s)
Dean M. DeLongchamp, P T. Hammond
This work applies the processing technique of layer-by-layer (LBL) assembly to the creation and development of new electrochemically-active composites. Layer-by-layer assembly is a type of assisted self-assembly that can create macromolecular complex films