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Search Publications by: Eliot Gann (Assoc)

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Displaying 1 - 25 of 38

Quantitative relationships between film morphology, charge carrier dynamics, and photovoltaic performance in bulk-heterojunction binary vs. ternary acceptor blends

February 7, 2023
Author(s)
Weigang Zhu, Guoping Li, Subhrangsu Mukherjee, Natalia Powers-Riggs, Leighton Jones, Eliot Gann, R Joseph Kline, Andrew Herzing, Jenna Logsdon, Lucas Flagg, Charlotte Stern, Ryan Young, Kevin Kohlstedt, George Schatz, Dean DeLongchamp, Michael Wasielewski, Ferdinand Melkonyan, Antonio Facchetti, Tobin Marks
Addressing pertinent and perplexing questions regarding why nonfullerene acceptors (NFAs) promote higher power conversion efficiencies (PCEs) than traditional fullerenes and how photoactive bulk heterojunction (BHJ) film morphology, charge photogeneration

Visualization of multi-orientational ordering within a single domain of donor non-fullerene acceptor blends

November 1, 2022
Author(s)
Eliot Gann, Christopher McNeill, Urvashi Bothra, Pramiti Hui, Wen Liang Tanc, Hariprasad Venugopal, Chandramouli Subramaniam, Amelia C.Y. Liu, Dinesh Kabra
We have studied the tailored micron-scale phase-separated bulk heterojunction (BHJ) morphology of the well-known polymer (PTB7-Th) and a narrow bandgap acceptor 2,2'-[[4,4,9,9-Tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno [1,2-b:5,6-b']dithiophene-2,7

Simulation-guided resonant soft X-ray scattering for determining microstructure of triblock copolymers

August 1, 2022
Author(s)
Eliot Gann, Veronica Reynolds, Michael L. Chabinyc, Christopher Bates, Devon Callan, Elizabeth Murphy, Yan-Qiao Chen, Kaitlin Albanese, Claire Wu, Craig Hawker
Resonant soft X-ray scattering (RSoXS) probes structure with chemical sensitivity that is useful for determining the morphology of multiblock copolymers. However, the hyperspectral data produced by this technique are challenging to interpret. Here, we use

Resonant X-ray Scattering in Polymer Science

April 1, 2022
Author(s)
Brian Collins, Eliot Gann
Resonant Soft X-ray Scattering (RSoXS) is an emerging, powerful technique to probe the nano-to-mesoscale ordering of polymers and other molecules. It joins together small-angle X-ray scattering (a statistical nanoprobe) with X-ray spectroscopy that brings

Reassessing the Significance of Reduced Aggregation and Crystallinity of Naphthalene Diimide-Based Copolymer Acceptors in All-Polymer Solar Cells

March 28, 2022
Author(s)
Eliot Gann, Christopher McNeill, Doan Vu, Martyn Jervic, Chao Wang, Lars Thomsen, Mats Andersson
Terpolymerization is a facile and effective strategy to control the aggregation and crystallinity of semiconducting polymers which has been exploited to improve the photovoltaic performance of all-polymer solar cells (all-PSCs). Applying this strategy to

Impact of Polymer Molecular Weight on Polymeric Photodiodes

November 29, 2021
Author(s)
Eliot Gann, Christopher McNeill, Lars Thomsen, Siddhartha Saggar, Kedar D Deshmukh, Monirul Hasan, Atul Shukla, Ebinazar B Namdas, Shih-Chun Lo, Jyoti S. Agawane, Nagaraj Nayak, Anil Kumar
The field of organic photodiodes has witnessed continuous development in the last decade. Although a considerable portion of electron-donating materials are polymers, there has been an existential gap in deciphering the influence of polymer chain length or

Polarized X-ray scattering measures molecular orientation in polymer-grafted nanoparticles

August 12, 2021
Author(s)
Subhrangsu Mukherjee, Dean DeLongchamp, Eliot Gann, Daniel Sunday, Lee J. Richter, Jason Streit, Richard A. Vaia, Baskar Ganapathysubramanian, Kumar Saurabh, Adarsh Krishnamurthy
Polymer chains are attached to nanoparticle surfaces for many purposes, including altering solubility, influencing aggregation, dispersion, and even tailoring immune responses in drug delivery. The most unique structural motif of polymer-grafted

Orientational ordering within semiconducting polymer fibrils

May 2, 2021
Author(s)
Subhrangsu Mukherjee, Eliot Gann, Masrur M. Nahid, Terry McAfee, Andrew Herzing, Dean DeLongchamp, Harald W. Ade
Due to a general paucity of suitable characterization methods, the internal orientational ordering of polymer fibrils has rarely been measured despite its importance particularly for semi-conducting polymers. An emerging tool with sensitivity to bond

Anisotropic resonant x-ray diffraction of a conjugated polymer at the sulfur K-edge

April 12, 2021
Author(s)
Eliot Gann, Christopher McNeill, Guillaume Freychet
The planar, aromatic nature of the backbone of conjugated polymers endow them with anisotropic properties. Here we show that the resonant x-ray diffraction of a sulfur containing semicrystalline conjugated polymer at the sulfur K-edge is highly anisotropic

A NIST facility for Resonant Soft X-ray Scattering measuring nano-scale soft matter structure at NSLS-II

January 26, 2021
Author(s)
Eliot Gann, Glenn Holland, R Joseph Kline, Peter Beaucage, Dean DeLongchamp, Daniel A. Fischer, Brian Collins, Terry McAfee, Christopher McNeill, Thomas Crofts
We present the design and performance of a Resonant Soft X-ray Scattering (RSoXS) station designed for soft matter characterization built by the National institute of Standards and Technology (NIST) at the National Synchrotron Light Source-II (NSLS-II)

Correlation of Nano-morphology with Structural and Spectroscopic Studies in Organic Solar Cells

October 27, 2020
Author(s)
Eliot Gann, Christopher McNeill, Wenchao Huang, Dinesh Kabra, Urvashi Bothra, Nakul Jain, Amelia C. Liu
The nano-morphology of bulk heterojunction blends based on poly[[4,8-bis[(2- ethylhexyl)oxy]benzo[1,2-b:4,5- b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7) blended with [6,6]- phenyl-C71-butyric acid methyl

Crucial role of fluorine in fully alkylated ladder type carbazole based nonfullerene acceptors for efficient organic solar cells

January 30, 2020
Author(s)
Eliot Gann, Christopher McNeill, He Qiao, Munazza Shahid, Xuchem Jiao, Flurin D. Eisner, Tingmang Wu, Zhuping Fei, Thomas D. Anthopoulos, Martin Heeney
Two fused ladder type nonfullerene acceptors, DTCCIC and DTCCIC-4F, based on an electron-donating core alkylated dithienocyclopentacarbazole flanked by electron-withdrawing non-fluorinated or fluorinated 1,1- dicyanomethylene-3-indanone (IC or IC-4F), are