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Search Publications by: David Raciti (Fed)

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Displaying 1 - 16 of 16

Bottom-up Au Filling of Trenches in Curved Wafers

March 4, 2024
Author(s)
Daniel Josell, Thomas P. Moffat, Thomas Gnaupel-Herold, David Raciti, Martin Stauber, Yu Q, Liyang Chen, M Rawlik, Marco Stampanoni, Lucia Romano
A 〖Bi〗^(3+)-stimulated Au electrodeposition process in slightly alkaline 〖Na〗_3 Au(〖SO〗_3 )_2+〖Na〗_2 〖SO〗_3 electrolytes has been previously demonstrated for void-free extreme bottom-up filling of trenches with aspect ratios (height/width) exceeding 60 in

SHINERS Study of Chloride Order-Disorder Phase Transition and Solvation of Cu(100)

January 3, 2024
Author(s)
Thomas P. Moffat, David Raciti, Angela R. Hight Walker, Eric J. Cockayne, John Vinson, Kathleen Schwarz
Shell-isolated Nanoparticle Enhance Raman Spectroscopy (SHINERS) and Density Functional Theory (DFT) are used to probe Cl- adsorption and the order-disorder phase transition associated with the c(2×2) Cl- adlayer on Cu(100) in acid media. A two-component 

CO Reduction on Single-atom Copper

July 26, 2023
Author(s)
Yuxuan Wang, Hao Shen, Bin Xue, Boyang Li, Nicole Libretto, Han Zong, Wenjun Xie, Ziyuan Li, Guangye Zhou, Jeffrey Vetik, Jeffrey T. Miller, Guofeng Wang, Chao Wang, David Raciti

Superconformal Film Growth: From Smoothing Surfaces to Interconnect Technology

April 20, 2023
Author(s)
Thomas P. Moffat, Trevor Braun, David Raciti, Daniel Josell
CONSPECTUS: State-of-the-art manufacturing of electronics involves the electrodeposition of Cu to form 3-D circuitry of arbitrary complexity. This ranges from nanometers wide interconnects between individual transistors to increasingly large multilevel

Potentiometric Rotating Ring Disk Electrode (RRDE) Study of Interfacial pH during CO2 Reduction and H2 Generation in Neutral and Weakly Acidic Media

April 21, 2022
Author(s)
Thomas P. Moffat, Nicole Ritzert, David Raciti, Brian Tackett, Nicholas Brady
Electrocatalytic reduction of CO2 to CO in aqueous media offers an important path to more sustainable carbon utilization. Optimization of this process relies on a detailed understanding of the dynamics of boundary layer chemistry, e.g., pH, adjacent to the

In-situ Stress Measurements During CO Adsorption onto Pt

February 24, 2022
Author(s)
David Raciti, Gery R. Stafford, Kathleen Schwarz, John Vinson
The change in surface stress associated with the adsorption and oxidative stripping of carbon monoxide (CO) on (111)-textured Pt is examined using the wafer curvature method in 0.1 M KHCO3 electrolyte. The curvature of the Pt cantilever electrode was

High Aspect Ratio Ag Nanowire Mat Electrodes for Electrochemical CO production from CO2

September 13, 2021
Author(s)
David Raciti, Trevor Braun, Brian M. Tackett, Heng Xu, Mutya Cruz, Benjamin Wiley, Thomas P. Moffat
An interconnected network of high-aspect ratio Ag nanowires was pressed against porous gas diffusion layers (both conductive or non-conductive) to use as a gas diffusion electrode (GDE) for the electrochemical reduction of CO2 to CO. Varying the amount of

Endothermic reaction at room temperature enabled by deep-ultraviolet plasmons

November 2, 2020
Author(s)
Canhui Wang, Wei-Chang Yang, David Raciti, Alina Bruma, Ronald Marx, Amit Agrawal, Renu Sharma
Sequestration and conversion of CO2 is a promising method for remedying climate change. However, current technologies remain limited due to infeasible system demands and outputs, such as high-temperature/pressure conditions, use of precious metals, or low

Copper Nanocubes for CO2 Reduction in Gas Diffusion Electrodes

October 31, 2019
Author(s)
Yuxuan Wang, Hao Shen, Ken J. Livi, David Raciti, Han Zong, John Gregg, Mofopefoluwa Onadeko, Yidong Wang, Adam Watson, Chao Wang
Electroreduction of CO2 represents a promising solution for addressing the global challenges in energy and sustainability. The reaction is highly sensitive to the surface structure of electrocatalysts and the local electrochemical environment. We have