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Fluid Characterization Group

The Fluid Characterization Group specializes in the development of novel methods for analyzing vapors and fluid mixtures to serve public health and safety, criminal justice, and industry.

The National Institute of Justice (NIJ) has awarded $1.5M in funding to support a NIST study towards reliable breath-based determination of recent cannabis use.

The Fluid Characterization Group is part of the Applied Chemicals and Materials Division (ACMD) on the NIST Boulder campus. We develop and validate novel methods and instrumentation for measurements of fundamental thermophysical properties such as vapor-liquid equilibrium (VLE), vapor-solid equilibrium (VSE), interaction parameters, vapor pressure, and competitive adsorption. We focus on challenging, real-world systems that contain trace compounds or reactive molecules, typically in complex mixtures.

Applications for our work include: GWP/GHG refrigerants, indoor air quality, forensics, exposure science, environmental science, energy technology, and numerous field sampling applications. We collaborate with industry, universities, and government agencies. We participate in several standards organizations to support the adoption of improved methods.

The group’s analytical capabilities are the product of an extensive suite of instrumentation and staff with years of specialized experience.

  • Gas chromatography equipped with a single quadrupole mass spectrometry (electron ionization GC-MS) and flame ionization detection (GC-FID);
  • High-resolution tandem quadrupole-time of flight mass spectrometer (GC-QTOF MS/MS);
  • High performance liquid chromatography with detection by UV-Vis spectrometry and quadrupole mass spectrometry (ESI/APCI);
  • Fourier-transform infrared spectroscopy (FTIR).

We operate a fully equipped nuclear magnetic resonance spectroscopy laboratory with a high-field (600 MHz NMR) spectrometry and a suite of NMR probes that allow for structural, dynamic, and diffusion measurements of gases, liquids, and solids as well as a 60 MHz benchtop NMR system.  

We maintain both the NMR Facility and the Biosafety Level 2 (BSL-2) Facilities at NIST Boulder. 

 

News and Updates

Recent Patent Activity within ACMD

A provisional patent by Tom Bruno and Kim Urness of the Applied Chemicals and Materials Division on Inductive Flash Desorption was published on June 7, 2018

Projects and Programs

Chemical Foundations for a Cannabis Breathalyzer

Ongoing
NIST's initial work in cannabis science was a series of measurements of the vapor pressure of two important cannabinoids: delta-9-tetrahydrocannabinol (THC) and cannabidiol (CBD). Our current effort is funded in part by interagency agreements with the ational Institute of Justice and by the NIST

Vapor Sampling to Support Public Safety and Forensics

Ongoing
Vapor pressures of unstable, reactive compounds. Over the last decade, our group has investigated a variety of low-volatility compounds including taggants (found in explosives), biofuels, terpenes and cannabinoids. Dynamic vapor microextraction (DVME), developed at NIST, is a small-volume dynamic

Fluid Phase Nuclear Magnetic Resonance (NMR) Spectroscopy

Ongoing
In-situ vapor-liquid equilibrium (VLE). We are applying vapor-phase NMR to measure VLE in-situ. We are currently applying this methodology to industrially important systems such as refrigerants and natural gas. The most widely used refrigerants have high global warming potential. Drop-in

Renewable Energy and Fuels

Ongoing
Fuel volatility and chemical characterization. We specialize in the Advanced Distillation Curve (ADC) method , developed at NIST, which is a powerful tool for the measurement of distillation curves to characterize complex fluids. We have applied this to simple hydrocarbons, gasolines, diesel fuels

NIST Tools for Cannabis Laboratory Quality Assurance

Ongoing
Since the 1970s, cannabis (marijuana and hemp) and its constituent, Δ 9-tetrahydrocannabinol or THC, have been classified as Schedule I controlled substances. Seized evidence is tested by forensic laboratories, which verify the identity of the plant through macro- and microscopic evaluation and the

Measuring Intermolecular Interactions with Electro-Acoustic Spectroscopy

Ongoing
We have a number of opportunities to collaborate with us. See below for details. What does this project aim to do for the chemical industry? Many industrial processes depend on the intermolecular environment- the solvents and ions that surround a molecule. These interactions impact separations

Awards

Publications

NMR Spectroscopy and Multiscale Modeling Shed Light on Ion–Solvent Interactions and Ion Pairing in Aqueous NaF Solutions

Author(s)
Gosia Musial, Demian Riccardi, Chris Suiter, Ethan Sontarp, Samantha Miller, Robert Lirette, Kyle Covington-Rehmeier, Avik Mahata, Chris Muzny, Angela Stelson, Kathleen Schwarz, Jason A. Widegren
The balance between ion solvation and ion pairing in aqueous solutions modulates chemical and physical processes from catalysis to protein folding. Yet, despite

Staff

Name Phone Number Email
Cheryle Beuning (303) 497-3383 cheryle.beuning [at] nist.gov (cheryle[dot]beuning[at]nist[dot]gov)
Jennifer (Jenny) Berry (303) 497-7033 jennifer.berry [at] nist.gov (jennifer[dot]berry[at]nist[dot]gov)
Kavita Jeerage (303) 497-4968 kavita.jeerage [at] nist.gov (kavita[dot]jeerage[at]nist[dot]gov)
Samantha (Sam) Miller   samantha.miller [at] nist.gov (samantha[dot]miller[at]nist[dot]gov)
Malgorzata (Gorza) Musial   malgorzata.musial [at] nist.gov (malgorzata[dot]musial[at]nist[dot]gov)
Chris Suiter (303) 497-4027 chris.suiter [at] nist.gov (chris[dot]suiter[at]nist[dot]gov)
Tara Lovestead (303) 497-5614 tara.lovestead [at] nist.gov (tara[dot]lovestead[at]nist[dot]gov)
Jason Widegren (303) 497-5207 jason.widegren [at] nist.gov (jason[dot]widegren[at]nist[dot]gov)


Alumni 

 

Name Phone Number Email
Adam Broerman  

 

Megan Harries    mharries [at] nas.edu (mharries[at]nas[dot]edu) (Program Officer for the Chemical Sciences and Technology at NASEM)

Michael Sartini

 

 

Kyle Covington   kyle.covington [at] nist.gov (kyle[dot]covington[at]nist[dot]gov)
Adam Friss  

adam.friss [at] nist.gov (adam[dot]friss[at]nist[dot]gov)

Zack Fishman (Guest Researcher)   zack.fishman [at] nist.gov (zack[dot]fishman[at]nist[dot]gov)
Katherine Zink (Guest Researcher)   katherine.zink [at] nist.gov (katherine[dot]zink[at]nist[dot]gov)

 

 

 

Contacts

Group Leader