Elemental characterization of Single-Wall Carbon Nanotube (SWCNT-1) reference material by neutron and prompt gamma activation analysis

Published

April 7, 2015

Author(s)

Rick L. Paul, Rabia Oflaz, Jan Kucera, J W Bennett, E. A. De Nadai Fernandes, M. Kubesova, M. A. Bacchi, A. J. Stopic, R. E. Sturgeon, P. Grinberg

Abstract

Instrumental neutron activation analysis with both relative and k0 standardization was used in four experienced laboratories to determine element mass fractions in single-wall carbon nanotube certified reference material (CRM) SWCNT-1. Results obtained were evaluated using the NIST “Type B On Bias” approach and yielded consensus values in agreement with NRCC certified values for Fe, Co, Ni and Mo and provided mass fractions for thirteen additional elements, namely Na, Mg, Al, K, Ca, Ti, V, Cr, Mn, Br, La, W and Au. In addition, prompt gamma neutron activation analysis was employed to determine mass fractions of H, B, Co, Ni, and Mo. Results of this work provide a basis for the establishment of reference values of element mass fractions in CRM SWCNT-1, thus expanding its usability for more accurate characterization and benchmarking of similar nanotechnology materials.

Citation

Analytical Chemistry

Volume

87

Issue

7

Pub Type

Journals

Keywords

nanotubes, nanotechnology, prompt gamma activation analysis, instrumental neutron activation analysis

Citation

Paul, R. , Oflaz, R. , , J. , , J. , , E. , Kubesova, M. , , M. , J., A. , Sturgeon, R. and Grinberg, P. (2015), Elemental characterization of Single-Wall Carbon Nanotube (SWCNT-1) reference material by neutron and prompt gamma activation analysis, Analytical Chemistry (Accessed January 15, 2025)