Mikaia, A.
and Zaikin, V.
(1980),
Ionization and appearance potentials in organic chemistry. 3. Determination of the difference between the enthalpies of formation of cis- and trans-isomers of bicyclo[4.3.0]- nonane and bicyclo[4.4.0]decane Using Appearance Potentials, Russian Chemical Bulletin
(Accessed July 17, 2024)
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Ionization and appearance potentials in organic chemistry. 3. Determination of the difference between the enthalpies of formation of cis- and trans-isomers of bicyclo[4.3.0]- nonane and bicyclo[4.4.0]decane Using Appearance Potentials
Published
Author(s)
, Vladimir G. Zaikin
Abstract
The first adiabatic potentials of the ionization of cis and trans iosmers with respect to the linkage of the rings of bicyclo[4.3.0]nonane and bicyclo[4.4.0]decane are practically identical. for the stereoisomers of these two series have been measured. The difference in the appearance potentials of the ions with a mass at 96 Da is equal to the difference in the enthalpy of formation of the geometric isomers, with a reversed sign.Citation
Russian Chemical Bulletin
Volume
6
Pub Type
Journals
Keywords
Electron ionization, Adiabatic potential, Appearance energy, bicyclo[4.3.0]nonane, bicyclo[4.4.0]decane
Citation
Issues
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Created June 1, 1980, Updated January 27, 2020