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Displaying 1176 - 1200 of 2122

ROLE OF SALT ON ADHESION OF AN EPOXY/ALUMINUM (OXIDE) INTERFACE IN AQUEOUS ENVIRONMENTS

November 5, 2015
Author(s)
Kar T. Tan, Christopher C. White, Donald L. Hunston, Justin M. Gorham, Michael Imburgia, Aaron M. Forster, Vogt D. Bryan
Engineering joints consisting of polymer/inorganic interfaces are commonly exposed to less than ideal conditions during normal service; these environmental conditions present a significant challenge for maintaining the structural integrity of the interface

The Fiber Break Evolution Process in a 2-D Epoxy/Glass Multi-Fiber Array

November 2, 2015
Author(s)
Edward D. McCarthy, Jae H. Kim, N. Alan Heckert, Stefan D. Leigh, Jeffrey W. Gilman, Gale A. Holmes
The mechanical integrity of a structural composite is strongly affected by the strength and toughness of the fiber-matrix interface/interphase [1], with interfacial shear strength (IFSS) being the accepted quanti-fying metric. However, the value of the

Magnetocaloric Response Of Non-Stoichiometric Ni(sub2)MnGa Alloys and the Influence of Texture

November 1, 2015
Author(s)
Michael V. McLeod, Anit Giri, Brigitte A. Paterson, Cindi L. Dennis, H L. Zhou, S C. Vogel, Yong Ho Sohn, Robert D. Shull, B S. Majumdar
Currently, there is significant interest in magnetocaloric materials for solid state refrigeration. In this work, polycrystalline Heusler alloys belonging to the Ni(sub2+x)Mn(sub 1-x) Ga family, with x between 0.08 and 0.24, were evaluated for the purpose

Order-Disorder and Phase Separation

October 28, 2015
Author(s)
Benjamin P. Burton
Order-disorder and phase separation in condensed solutions of two or more components are similar processes that are typically driven by energetics of opposite sign. The components may be: different atomic species in alloys or solid solutions; atoms and

A Scanning Probe Investigation of the Role of Surface Motifs in the Behavior of p-WSe(sub2) Photocathodes

October 8, 2015
Author(s)
Jesus M. Velazquez, Jimmy John, Daniel V. Esposito, Adam Pieterick, Ragip Pala, Guofeng Sun, Xinghao Zhou, Zhuangqun Huang, Shane Ardo, Bruce S. Brunschwig, Nathan S. Lewis
The spatial variation in the properties and performance of bare and Pt-decorated p-type WSe(sub2) photocathodes has been investigated by using Scaning Photocurrent Microscopy (SPCM) and Local Spectral Response in solution. Microscale SPCM measurements

Cosolvency and cononsolvency explained in terms of a Flory-Huggins type theory

October 7, 2015
Author(s)
Jack F. Douglas, Jacek Dudowicz, Freed Karl
Standard classic Flory-Huggins (FH) theory is employed to describe the enigmatic cosolvency and co-nonsolvency phenomena for systems of polymers dissolved in mixed solvents. In particular, phase boundaries (spinodals) are calculated for solutions of

Assessment of Water Vapor Diffusion in Firefighter’s Protective Clothing

October 1, 2015
Author(s)
Shonali Nazare, Christopher W. Meyer, Daniel M. Madrzykowski
Structural firefighters often encounter hot and humid environments during interior firefighting. The water vapor transfer to and from the skin has great influence on thermo-physiological comfort of the firefigher. Quantitative information on water vapor

Assessing the Thermal Protective Performance of Fire Blocking Barrier Fabrics for Residential Upholstered Furniture: Report to Consumer Product Safety Commission for Interagency Agreement CPSC-I-13-0022

September 17, 2015
Author(s)
Shonali Nazare, John R. Shields, Szabolcs Matko, Rick D. Davis
Fire behavior of five barrier fabrics has been evaluated both, as an individual component and as a part of composite samples, using different test methods. The quantitative component test methods selected to characterize fire behavior of barrier fabrics

Structural origins of enhanced capacity retention in novel copolymerized sulfur-based composite cathodes for high-energy density Li-S batteries

September 17, 2015
Author(s)
Vladimir P. Oleshko, Jenny J. Kim, Jennifer L. Schaefer, Steven D. Hudson, Christopher L. Soles, Adam Simmonds, Jared Griebel, Kookheon Char, Jeff Pyun
Poly(sulfur-random-(1,3-diisopropenylbenzene) (poly(S-r-DIB)) copolymers synthesized via inverse vulcanization form high molecular mass electrochemically active polymers capable of realizing enhanced capacity retention (1005 mAh/g at 100 cycles) and

When does a branched polymer becomes a particle?

September 17, 2015
Author(s)
Alexandros Chremos, Jack F. Douglas
Melts with topologically distinct molecular structures are investigated by molecular dynamics simulation. We determine the mean polymer size and shape, and glass transition temperature for each molecular topology. Both in terms of structure and dynamics

Self-terminated Electrodeposition of Iridium Electrocatalysts

September 16, 2015
Author(s)
Thomas P. Moffat
A simple electrochemical process for submonolayer deposition of ultrathin catalytic iridum (Ir) films is demonstrated. The process enables effective utilization of one of nature’s rarest elements while different substrates facilitate the exploration of

Stress in Aluminum Induced by Hydrogen Absorption during Cathodic Polarization

September 16, 2015
Author(s)
Gery R. Stafford, Jae W. Shin, Kurt Hebert
The hydrogen concentration in metals during aqueous corrosion is influenced by the kinetics of hydrogen absorption. Measurements of absorption kinetics are challenged by competing gas evolution and corrosion processes. However, in situ measurements of

The Osmotic Virial Repersentation of the Free Energy of Polymer Mixing

September 14, 2015
Author(s)
Jack F. Douglas, August W. Bosse
In this Letter we derive a new representation of the free energy of polymer mixing. We begin with a Flory-Huggins-like free energy of mixing, and assume that the excess free energy of mixing exhibits an arbitrary dependence on the blend composition that
Displaying 1176 - 1200 of 2122