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Displaying 151 - 175 of 188

Amplification of the optical absorption cross section for aerosols of soot with a nonabsorbing coating from photoacoustic measurements

May 13, 2011
Author(s)
Pedro Bueno, Daniel K. Havey, George W. Mulholland, Joseph T. Hodges, Keith A. Gillis, Russell R. Dickerson, Michael R. Zachariah
A quantitative understanding of the absorption and scattering properties of mixed soot and aerosol particles is necessary for evaluating the Earth's energy balance. Uncertainty in the net radiative forcing of atmospheric aerosols is relatively large and

Dual comb spectroscopy from 1.25 to 1.7 ym

May 1, 2011
Author(s)
Alexander M. Zolot, Ian R. Coddington, Fabrizio R. Giorgetta, Esther Baumann, William C. Swann, Nathan R. Newbury
A coherent dual comb spectrometer spanning much of the near infrared was constructed from broadened erbium fiber lasers. Gas phase water, methane and acetylene spectra were measured and characterized toward establishing new frequency standards.

Ozone-Depleting Substances (ODSs) and Related Chemicals, Chapter 1 in Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project-Report No.52, 516 pp., World Meteorological Organization, Geneva, Switzerland, 2011.

March 30, 2011
Author(s)
Stephen A. Montzka, S. Reimannander, Andreas Engel, Kirstin Kruger, O?Doherty Simon, William T. Sturges , Donald R. Blake , Marcel Dorf Dorf, Paul J. Fraser , Lucien Froidevaux , Kenneth Jucks, Karin Kreher, Michael J. Kurylo III, Abdelwahid Mellouki , John Miller , Ole J. Nielsen , Vladimir L. Orkin, Ronald G. Prinn , Robert Rhew , Michelle L. Santee , Andreas Stohl , Daniel P. Verdonik
The present document will be part of the information upon which the Parties to the United Nations Montreal Protocol will base their future decisions regarding protection of the stratospheric ozone layer. OVERVIEW It has been recognized since the 1970s that

Quantification and Compensation of Unintentional Analyte Aggregation in Electrospray Sampling

March 30, 2011
Author(s)
Mingdong M. Li, Suvajyoti S. Guha, Rebecca A. Zangmeister, Michael J. Tarlov, Michael R. Zachariah
Electrospray (ES) sources are commonly used to introduce non-volatile materials (e.g. nanoparticles, proteins, etc.) in to the gas phase for characterization by mass spectrometry and ion mobility. Recent studies in our group using electrospray ion mobility

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the

Rate Constants for the Reactions between OH and Perfluorinated Alkenes

February 20, 2011
Author(s)
Vladimir L. Orkin, Gregory A. Poskrebyshev, Michael J. Kurylo III
The rate constants for the reactions of OH radicals with fully fluorinated alkenes containing different number of –CF3 groups next to olefinic carbon, CF2=CF2, CF2=CFCF3, CF3CF=CFCF3, (CF3)2C=CFC2F5 were measured using the flash photolysis resonance

Performance of a coherent dual frequency comb spectrometer

January 1, 2011
Author(s)
Nathan R. Newbury, Esther Baumann, Ian R. Coddington, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
We discuss the performance of a coherent dual frequency comb spectrometer in terms of signal-to-noise ratio, resolution, and accuracy based on experimental data in the near and short-wave infrared centered at 1.5 and 3.4 micrometers.

Broadband coherent spectroscopy in the near infrared using dual coherent frequency combs

August 15, 2010
Author(s)
Nathan R. Newbury, Ian R. Coddington, Esther Baumann, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
Fiber-based frequency combs can provide broadband coherent light that enables new possibilities for high-accuracy, high-resolution broadband spectroscopy. We use a configuration with two coherently phase-locked combs; the output of one comb passes through

Standard Photoacoustic Spectrometer: Model and Validation using O2 A-Band Spectra

June 30, 2010
Author(s)
Keith A. Gillis, Daniel K. Havey, Joseph T. Hodges
We model and measure the absolute response of an intensity-modulated photoacoustic spectrometer comprising a 10 cm long resonator and having a Q-factor of approximately 30. We present a detailed theoretical analysis of the system and predict its response

Kinetics of the Thermal Reaction of H Atoms with Propyne

April 15, 2010
Author(s)
Claudette M. Rosado-Reyes, Jeffrey A. Manion, Wing Tsang
The reaction of hydrogen atoms with propyne(CH≡CCH3) has been investigated in a heated single pulse shock tube at temperatures of 870-1145K and pressures of 2-9 bar. Stable products from various reaction channels (terminal and non-terminal H addition, and

A proposed global atmospheric monitoring networkbased on standard stars

November 2, 2009
Author(s)
Gerald T. Fraser, Steven W. Brown, Keith R. Lykke, John T. McGraw, Allan W. Smith, John T. Woodward IV, Peter C. Zimmer, Christopher W. Stubbs
The feasibility of developing a network of telescopes to monitor the composition of the nighttime atmosphere using stellar spectrophotometry is explored. Spectral measurements of the extinction of starlight by the atmosphere would allow, for instance
Displaying 151 - 175 of 188