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Displaying 201 - 225 of 524

Organohalogen contaminants and vitamins in Northern Fur Seals (Callorhinus ursinus) collected during subsistence hunts in Alaska

January 1, 2016
Author(s)
Jessica L. Reiner, Paul R. Becker, Jennifer M. Lynch, Amanda J. Moors, Jennifer M. Ness, Rebecca S. Pugh, Catherine A. Rimmer, John R. Kucklick, Matthew O. Gribble, Danielle Peterson, Jody Rhoderick, Jennifer Trevillian
During native subsistence hunts from 1987 to 2007, blubber and liver samples from 50 subadult male northern fur seals (Callorhinus ursinus) were collected on St. Paul Island, Alaska. Samples were analyzed for legacy persistent organic pollutants (POPs)

Urinary iodine and stable isotope analysis to examine habitat influences on thyroid hormones among coastal dwelling American alligators

December 9, 2015
Author(s)
Ashley S. Boggs-Russell, Heather J. Hamlin, James C. Nifong, Brittany L. Kassim, Russell H. Lowers, Thomas M. Galligan, Stephen E. Long, Louis J. Guillette Jr.
The American alligator, a freshwater species, is known to forage in marine environments which could lead to increased dietary uptake of iodine, a nutrient necessary for the production of thyroid hormones. To explore the influence of dietary iodine on

Comparison of halocarbon measurements in an atmospheric dry whole air sample

November 3, 2015
Author(s)
George C. Rhoderick, Bradley Hall, Christina Harth, Jin Seog Kim, Jeogsoon Lee, Stephen Montzka, J. Muhle, Stefan Reimann, Martin Vollmer, Ray Weiss
The growing awareness of climate change/global warming, and continuing concerns regarding stratospheric ozone depletion, will require continued measurements and standards for many compounds, in particular halocarbons that are linked to these issues. In

Hitting the bounds of chemistry: Limits and tradeoffs for low-GWP refrigerants.

August 19, 2015
Author(s)
Mark O. McLinden, J. Steven Brown, Andrei F. Kazakov, Piotr A. Domanski
We explore the possibilities for low-GWP refrigerants through two approaches. First, we explore the performance of hypothetical refrigerants to define the limits of what is allowed by thermodynamics. In the second approach, we apply property estimation

Perfluorinated Alkyl Acids in Wildlife

April 21, 2015
Author(s)
Jessica L. Reiner, Benjamin J. Place
The first measurements of perfluorinated compounds (PFCs) in wildlife from the aqueous and terrestrial environment showed their ubiquitous presence. Since the initial studies in 2001 their presence, distribution, and fate in the environment has broadly

A Fundamental Equation of State for 1,1,1,3,3-Pentafluoropropane (R-245fa)

March 26, 2015
Author(s)
Ryo Akasaka, Yong Zhou, Eric Lemmon
A new fundamental equation of state explicit in the Helmholtz energy is presented for 1,1,1,3,3 pentafluoropropane (R 245fa), based on recent experimental data for the vapor pressures, densities, and vapor sound speeds. The functional form now uses

Reference Diffraction Patterns, Microstructure, and Pore Size Distribution for the Copper (II) benzene-1,3,5-tricarboxylate Metal Organic Framework (Cu-BTC) Compounds

March 1, 2015
Author(s)
Winnie K. Wong-Ng, James A. Kaduk, Daniel W. Siderius, Andrew J. Allen, Laura Espinal, Brad Boyerinas, Igor Levin, Matthew Suchomel, Jan Ilavsky, Eric J. Cockayne, Hui Wu
Cu-paddle-wheel-based Cu3(BTC)2 (nicknamed Cu-BTC, where BTC ≡ benzene 1,3,5-tricarboxylate) is a metal organic framework (MOF) compound that adopts a zeolite topology. We have determined the pore size distribution using the Gelb and Gubbins technique, the

Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, Chapter 1 in Scientific Assessment of Ozone Depletion: 2014, Global Ozone Research and Monitoring Project-Report No.55, 416 pp., World Meteorological Organiz

December 30, 2014
Author(s)
Lucy J. Carpenter, Stefan Reimann, Andreas Engel, Stephen Montzka, James B. Burkholder, Cathy Clerbaux, Bradley Hall, Shari A. Yvon-Lewis, Donald R. Blake, Marcel Dorf, Geoffre S. Dutton, Paul J. Fraser, Lucien Froidevaux, Fran?ois Hendrick, Jianxin Hu, Ashley Jones, Paul B. Krummel, Lambert J. Kuijpers, Michael J. Kurylo, Qing Liang, Emmanuel Mahieu, Jens M?hle, Simon O?Doherty, Keiichi Ohnishi, Vladimir L. Orkin, Klaus Pfeilsticker, Matt Rigby, Isobel J. Simpson, Yoko Yokouchi
Changes in the global atmospheric abundance of a substance are determined by the balance between its emissions and removal. Declines observed for ozone-depleting substances (ODSs) controlled under the Montreal Protocol are due to global emission reductions

Interrogating the Carbon and Oxygen K-edge NEXAFS of a CO2-dosed Hyperbranched Aminosilica

December 19, 2014
Author(s)
Laura Espinal, Martin L. Green, Dean M. DeLongchamp, Watcharop Chaikittisilp, Jarod C. Horn, Miles Sakwa-Novak, Cherno Jaye, Daniel A. Fischer, Nicholas Brunelli, Christopher Jones
Near edge x-ray absorption fine structure (NEXAFS) spectroscopy was used to study the adsorption of CO2 in a hyperbranched aminosilica (HAS) compound, a porous solid state material with great potential for carbon capture applications. After dosing a

Biomass Particle Models with Realistic Morphology and Resolved Microstructure for Simulations of Intraparticle Transport Phenomena

December 9, 2014
Author(s)
Peter Ciesielski, Michael F. Crowley, M R. Nimlos, Aric Sanders, Gavin Wiggins, Bryon Donohoe
Biomass exhibits a complex microstructure of directional pores that can vary substantially between species of origin. However, models of biomass particles employed in simulations of conversion processes typically employ over-simplified geometry such as

Assessment of Crude Oil and a Dispersant in a Simulated Spartina alterniflora Salt Marsh Ecosystem

December 1, 2014
Author(s)
P Key, K Chung, C Cooksey, DeLorenzo M, M Fulton, D Greenfield, T Greig, J Hylund, Bryant C. Nelson, Varun Patel, P Pennington, Elijah Petersen, E Wirth
NOAA's Environmental Sensitivity Index (ESI) lists saltmarshes along the Atlantic and Gulf Coasts as the most vulnerable habitat to oil spills. As a result of the Deepwater Horizon offshore drilling rig accident, more that 200 million gallons of crude oil

Principles of Optical Radiometry and Measurement Uncertainty

November 27, 2014
Author(s)
Bettye C. Johnson, Howard W. Yoon, Joseph P. Rice, Albert C. Parr
The fundamental concepts of optical radiometry are developed from basic principles, with detailed explanations for radiance, irradiance, and reflectance. Examples of radiometric standards, in particular radiometers and reference sources are given, and the

Photochemical Properties of Hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: Reactivity toward OH, IR Absorption Cross Sections, Atmospheric Lifetimes and Global Warming Potentials

September 22, 2014
Author(s)
Vladimir L. Orkin, Victor Khamaganov, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially fluorinated ethers, CH3OCF3 (kHFE-143a), CH3OCHF2 (kHFE-152a), and CHF2OCH2CF3 (kHFE-245fa), were measured using a discharge flow – electron paramagnetic resonance technique

Effects of Temperature on Surface Accumulation and Release of Silica Nanoparticles in an Epoxy Nanocoating Exposed to UV Radiation

June 16, 2014
Author(s)
Chun-Chieh Tien, Ching-Hsuan Chang, Bernard Hao-Chih Liu, Deborah Jacobs, Savelas A. Rabb, Lee L. Yu, Tinh Nguyen, Li Piin Sung
Polymer nanocoatings are increasingly used outdoors and in harsh environments. However, because most common polymers degraded by the weathering elements, nanoparticles in polymer nanocoatings may be released into the environments. Such nanoparticle release
Displaying 201 - 225 of 524