U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

PUBLICATIONS

Structure and Spectroscopy of Hydrogen Adsorbed in a Nickel Metal-Organic Framework

Published

Author(s)

Craig M. Brown, Anibal Javier Ramirez-Cuesta, Jae-Hyuk Her, Paul S. Wheatley, Russell E. Morris

Abstract

The structure of Ni2(dobdc) (dobdc4- = 2,5- dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in-situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogues and the Ni2+ variant shows the shortest deuterium-metal distance in the M2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.
Citation
Chemical Physics
Volume
427
Pub Type
Journals

Download Paper

Local Download

Keywords

hydrogen storage, neutron scattering, neutron diffraction, lnelastic neutron scattering, metal organic framework

Citation

Brown, C. , , A. , Her, J. , , P. and , R. (2013), Structure and Spectroscopy of Hydrogen Adsorbed in a Nickel Metal-Organic Framework, Chemical Physics, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=914364 (Accessed July 18, 2024)

Issues

If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.

Created December 12, 2013, Updated February 19, 2017