U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Search Publications by: R Joseph Kline (Fed)

Search Title, Abstract, Conference, Citation, Keyword or Author
Displaying 126 - 150 of 174

Nanoscale structure measurements for polymer-fullerene photovoltaics

February 3, 2012
Author(s)
Dean M. DeLongchamp, Regis J. Kline, Andrew A. Herzing
This review covers methods to measure key aspects of nanoscale structure in organic photovoltaic devices based on polymer-fullerene bulk heterojunctions. The importance of nanoscale structure to the power conversion efficiency and stability of these

Molecular Order in High-Efficiency Polymer/Fullerene Bulk Heterojunction Solar Cells

September 22, 2011
Author(s)
Matthew R. Hammond, Regis J. Kline, Andrew A. Herzing, Lee J. Richter, David Germack, Hyun W. Ro, Christopher L. Soles, Daniel A. Fischer, Tao Xu, Luping Yu, Michael F. Toney, Dean M. DeLongchamp
We report quantitative measurements of ordering, molecular orientation, and nanoscale morphology in the active layer of bulk heterojunction organic photovoltaic cells based on a thieno[3,4-b]thiophene-alt-benzodithiophene copolymer (PTB7), which has been

Characterization of the non-uniform reaction in chemically-amplified calix[4]resorcinarene molecular resist thin films

July 19, 2011
Author(s)
Vivek M. Prabhu, Shuhui Kang, Regis J. Kline, Dean M. DeLongchamp, Daniel A. Fischer, Wen-Li Wu, Sushil K. Satija, Jing Sha, Christopher K. Ober, Peter V. Bonnesen
The ccc stereoisomer-purified tert-butoxycarbonyloxy (t-Boc) protected calix[4]resorcinarene molecular resists blended with photoacid generator exhibit a non-uniform photoacid catalyzed reaction in thin films. The surface displays a reduced reaction extent

Controlling the Microstructure of Solution-Processible Small Molecules in Thin-Film Transistors through Substrate Chemistry

February 4, 2011
Author(s)
Regis J. Kline, Steven D. Hudson, Xinran Zhang, David J. Gundlach, Andrew Moad, Lee J. Richter, Oana Jurchescu, Thomas Jackson, Sanker Subramanian, John E. Anthony, Michael F. Toney
Solution-processible small molecules have tremendous potential for providing both high charge carrier mobility and low cost processing. This study outlines a detailed microstructural study of the effect of substrate chemistry on fluorinated 5,11-bis

Influence of substrate on crystallization in polythiophene/fullerene blends

January 13, 2011
Author(s)
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general

Zone-Refinement Effect in Small Molecule-Polymer Blend Semiconductors for Organic Thin Film Transistors

December 14, 2010
Author(s)
Yeon Sook Chung, Nayool Shin, Jihoon Kang, Youngeun Jo, Vivek Prabhu, Regis J. Kline, John E. Anthony, Do Y. Yoon
The blend films of small molecule semiconductors with insulating polymers exhibit not only an excellent solution processability, but also superior performance characteristics (field-effect mobility, on/off ratio, threshold voltage and stability) over those

Controlling the Formation and Orientation of Terraced Nanoscale Ribbons of a Thiophene-Based Copolymer

March 24, 2009
Author(s)
Dean M. DeLongchamp, Regis J. Kline, Youngsuk Jung, David Germack, Eric K. Lin, Andrew Moad, Lee J. Richter, Michael F. Toney, Martin Heeney, Iain McCulloch
Terraced nanoscale ribbon domains of a poly(2,5-bis(3-alkylthiophen-2-yl) thieno[3,2-b]thiophene) form after thin films are cooled from its highest-temperature phase. A simple flow coating procedure can induce high levels of ribbon orientation and even

Semiconducting Thienothiophene Copolymers: Design, Synthesis, Morphology and Performance in Thin Film Organic Transistors

March 1, 2009
Author(s)
Iain McCulloch, Martin Heeney, Michael L. Chabinyc, Dean DeLongchamp, Regis J. Kline, Michael Colle, Warren Duffy, Daniel A. Fischer, David J. Gundlach, Behrang Hamadani, Rick Hamilton, Lee J. Richter, Alberto Salleo, Martin Shkunov, David Sparrowe, Steve Tierney, Weimin Zhang
Organic semiconductors are emerging as a viable alternative to amorphous silicon in a range of thin film transistor devices. , With the possibility to formulate these p-type materials as inks and subsequently print into patterned devices, organic based

The molecular basis of mesophase ordering in a thiophene-based copolymer

February 18, 2009
Author(s)
Dean M. DeLongchamp, Regis J. Kline, Youngsuk Jung, Eric K. Lin, Daniel A. Fischer, David J. Gundlach, Andrew Moad, Lee J. Richter, Michael F. Toney, Martin Heeney, Iain McCulloch
The carrier mobility of poly(2,5-bis(3-alkylthiophen-2-yl) thieno[3,2-b]thiophene) semiconductors can be substantially enhanced after heating through a thermotropic mesophase transition, which causes a significant improvement in thin film structural order